How exactly does the oxidation of TEMPO by NaOCl/KBr work?
A simple google search tells me you found this mechanism off Sigma-Aldrich page on TEMPO oxidation, not exactly a reliable source. Looks like poorly drawn mechanism.
organic chemistry - How can the oxidation of TEMPO be selective ...
Sep 14, 2021 · According to the article " TEMPO oxidizes alcohols to aldehydes and ketones ", the oxidation of TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl, 2564-83-2) can be highly …
Mechanism for oxidation of primary alcohols to carboxylic acids
Jan 5, 2016 · My teacher told me that the following is the mechanism for oxidation of primary alcohols to carboxylic acids: I've searched in books and online and didn't find a similar …
Mechanism of oxidative dearomatisation with hypervalent iodine
Apr 20, 2019 · Being a high-valent iodine species, it is used as an oxidising agent in organic chemistry. So clearly, there is some sort of oxidation taken place in this step, along with …
Dependence of primary alcohol oxidation on presence of water …
Mar 7, 2019 · The determinant factor of the products obtained from an oxidation reaction of primary alcohols is the presence of water in the reaction medium, as it allows the formation of …
TEMPO Radical Analogue - Chemistry Stack Exchange
Feb 25, 2021 · After investigating what makes the persistent radical TEMPO stable, I was wondering if another compound which is more feasible for my needs would be comparable to …
organic chemistry - What's the chemical reaction between NaOCl …
Jan 16, 2021 · I doubt the reaction occurs as written. The transformation from left to right is not due to the $\ce {OCl^-}$ ion. No. It is due to the addition of $\ce {H2O}$ and this addition is …
Dess–Martin oxidation work up - Chemistry Stack Exchange
Mar 25, 2017 · I'm doing an oxidation of an alcohol with Dess–Martin periodinane which works really well but having trouble with the work up. Doing this reaction with about 5 g of alcohol so …
Mechanism of Jones oxidation - Chemistry Stack Exchange
May 17, 2024 · The mechanism begins with the reaction of $\ce {CrO3}$ with acid $ (\ce {H2SO4})$ to form chromic acid or dichromic acid in more concentrated solutions: The …
Mechanism of the oxidation of alcohols with KMnO4
May 21, 2015 · Many oxidising agents, like chromate, dichromate, iodine in $\\ce{NaOH}$ etc. seem to work via ester formation and elimination. For example, chromic acid will react with the …